基于BP神经网络的复合污染体系中沉积物吸附阿特拉津的规律   总被引：1，自引：0，他引：1  

李鱼  王倩  高茜  王岙 《吉林大学学报(地球科学版)》2011,(Z1):315-321

建立了Cu2+和阿特拉津(AT)复合污染体系中沉积物各活性组分及其交互作用对AT吸附量影响的BP神经网络模型,模型预测值和实验值的相关系数达到0.97,各集合的平均偏差均小于10%。模型显示,AT在沉积物上的主要吸附位是铁氧化物。沉积物吸附AT时铁氧化物、锰氧化物、有机质之间存在显著的交互作用,铁氧化物、锰氧化物交互作用贡献率为-130%～80%,铁氧化物、有机质交互作用贡献率为5%～28%,锰氧化物、有机质交互作用贡献率为-200%～-70%。各活性组分吸附AT的能力及其交互作用受Cu2+的影响较大,其中:Cu2+对AT在铁氧化物上的吸附表现为拮抗作用,对AT在锰氧化物上的吸附表现为协同作用,而对AT在有机质上的吸附影响不显著,同时Cu2+减弱了铁氧化物-锰氧化物和锰氧化物-有机质的交互作用影响,增强了铁氧化物-有机质的交互作用影响。  相似文献   

上海湖沼平原地貌分界线上地层分布特征研究   总被引：1，自引：0，他引：1  

孙莉 《上海国土资源》2011,32(4):68-72

上海湖沼平原和滨海平原地貌类型划分应遵从地貌特征,为工程应用方便,可划分地貌亚区。地貌分界线上典型的地质剖面,为湖沼平原第一硬土层与滨海平原暗绿色硬土层属于同一地质时代提供了直接证据。由于古河道、台地等古地貌特征,造就了不同地貌及地貌亚区之间地层差异。  相似文献   

浙江南部近海沉积物柱状样中脂类生物标志物的组成及形态分布     

王江涛  杨庶  谭丽菊  胡佶 《海洋学报》2011,33(5):83-90

分析了浙江南部近海(东海陆架泥质区)沉积物柱状样中游离态和碱不稳定结合态脂类生物标志物的组成.沉积物中的脂肪酸呈现以C16脂肪酸为主峰的单峰形分布趋势,具明显偶碳优势,除表层沉积物中脂肪酸以游离态为主外,结合态为柱状样中脂肪酸的主要存在形态,脂肪酸的垂直分布主要由降解作用控制;以甾醇和脂肪醇为主体的醇酮组分主要以游离态...  相似文献   

Seasonal variation of suspended-sediment transport through the southern Bohai Strait   总被引：2，自引：0，他引：2  

Naishuang Bi  Zuosheng Yang  Houjie Wang  Dejiang Fan  Xiaoxia Sun  Kun Lei 《Estuarine, Coastal and Shelf Science》2011

Based on field observations made in winter 2006 and summer 2007 and on multiscene MODerate resolution Imaging Spectrometer (MODIS) imagery, the seasonal variation of suspended-sediment transport in the southern Bohai Strait and its possible mechanisms are examined. The field observations in two different seasons allow an exponential empirical model to be used to retrieve suspended-sediment concentration (SSC) from MODIS imagery. Both the field-survey data and the MODIS-derived SSC show that the sediment transport in the southern Bohai Strait has a significant seasonal variation due to the seasonally varying thermohaline structure of the water column and the hydrodynamics resulting from the seasonally alternating monsoons. The SSC in winter is approximately 3–10 times higher than in summer. Considering the seasonal variation of water flux (WF) and SSC, the annual sediment flux (SSF) through the southern Bohai Strait is estimated to be approximately 40.0 Mt yr⁻¹, about 4–8 times previous estimates, which did not take into account seasonal variation. Although the Huanghe (Yellow River) discharges a large amount of sediment in the summer, the SSF through the southern Bohai Strait in the winter (∼32.0 Mt) is about 4 times greater than it is in the summer. The strong seasonal variability of SSF through the southern Bohai Strait indicates that strong resuspension along the coast of the Huanghe delta in winter and enhanced longshore transport by coastal currents due to winter monsoon activity might be the major mechanisms of cross-strait transport of sediment in winter.  相似文献   

Metal binding by humic acids in recent sediments from the SW Iberian coastal area     

J.M. De la Rosa  M. SantosM.F. Araújo 《Estuarine, Coastal and Shelf Science》2011

The concentrations of Cu, Zn, Cr, Ni, Pb, As, Mn and Co were determined by Inductively Coupled Plasma–Mass Spectrometry both in recent sediments from different locations of the Huelva littoral (SW Iberian Peninsula) and in their humic acid (HA) fractions in order to evaluate distribution and binding capacity of those trace elements to HAs. In addition, elemental composition (C, N, S) and δ¹³C values were determined to appraise the sources of organic matter in the area. This study involved the comparison of selected samples taken from different environments including the estuary of the Guadiana River, the main fluvial system of the region, the Tinto and Odiel estuary system and the proximal shelf. Significant positive correlations were found among Cu, Zn, As and Pb in bulk sediments, suggesting a common origin of all of those elements: the mining activities and pyrite deposits located hinterland. On the other hand, results for Cr, Co and Ni pointed to the basic rocks from the low basin of the Guadiana River as their main source. Elemental (C, N) and isotopic (δ¹³C) composition of sediments indicated a significant contribution of autochthonous plankton in coastal shelf sediments, whereas estuarine and riverine sediments showed a major contribution of terrestrial biomass. Geochemical values for their corresponding HAs suggested a greater terrestrial contribution in the sedimentary OM of the coastal shelf sediments than in bulk sediments, which evidenced the influence of coastal currents and sediment fluxes. Humic acids sequester considerable amounts of Cu and Zn contributing to reduce the bioavailability of these contaminants.  相似文献   

珠江三角洲晚第四纪红树林的演化及其环境意义     

翁毅  张伟强 《台湾海峡》2011,30(2):264-268

广州番禺东涌剖面样品的AMS（磁谱仪）年龄及红树林孢粉分析结果表明,珠江三角洲存在晚更新世和全新世的红树林,红树林是海侵的标志之一.按照检出红树属花粉的9个剖面的分布以及5处埋藏红树林腐木的分布,可以描绘出全新世海侵的边界.根据东涌剖面的沉积旋回、样品年龄、红树林花粉含量曲线、半咸水-淡水硅藻及热性-温性硅藻含量曲线的综合分析,可将沉积环境的变迁分为4个阶段.第一阶段和第三阶段的海侵有利于红树林的发展,第二阶段不利于红树林的发展,第四阶段的晚全新世,红树林的生长频繁,显示人为因素的影响.  相似文献   

Feeding strategies of deep-sea sub-Arctic macrofauna of the Faroe-Shetland Channel: Combining natural stable isotopes and enrichment techniques     

E. Gontikaki  D.J. MayorB.E. Narayanaswamy  U. Witte 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(2):160-172

The response of a sub-arctic, deep-sea macrofaunal community to a simulated food sedimentation event was studied by means of a stable isotope “pulse-chase” experiment. A food pulse was simulated by adding 500 mg C m⁻² of ¹³C-labelled diatoms, Chaetoceros radicans, to sediment cores retrieved from 1080 m in the Faroe-Shetland Channel. Carbon uptake by specific macrofaunal groups was quantified after 3 and 6 days of incubation. The carbon uptake of the dominant taxon (Polychaeta) was quantified at the genus-, and where possible, species-level, representing a data resolution that is rare in deep-sea tracer studies. The macrofaunal community reacted rapidly to the diatom addition, with 47% and 70% of the animals illustrating ¹³C-enrichment after 3 and 6 days, respectively. Approximately 95% of C uptake was located in the upper 2 cm due to the particularly shallow vertical distribution of the macrofaunal community and the nonexistent tracer subduction by burrowing species. Polychaetes of the families Ampharetidae and Cirratulidae were among the most heavily labelled with above background enrichment reaching 1300‰. Approximately 0.8 and 2.0 mg C m⁻² were processed by the macrofauna after 3 and 6 days, representing 0.2% and 0.4% of the added carbon, respectively. It was not possible to differentiate sub-surface deposit-feeding polychaetes from predator/scavenger- and omnivorous polychaetes using their natural ??¹⁵N signatures. However, the combination of natural abundance ??¹⁵N data and ¹³C-labelling experiments proved to be useful for elucidating trophic relations in deep-sea food webs. This study confirms that macrofauna play an active role in the short-term carbon cycling at bathyal depths even at sub-zero temperatures and highlights the need for detailed knowledge of the community structure in understanding carbon processing patterns and early diagenesis of organic matter in marine sediments.  相似文献   

西菲律宾海比科尔陆架深海沉积物古菌多样性研究     

格根塔娜  萨仁高娃  于心科  李铁刚  周伟光 《海洋科学》2011,35(11):4-10

通过构建16S rRNA 基因文库, 对西太平洋西菲律宾海东板比科尔陆架5 个不同层位沉积物样品中的古菌的多样性进行了研究, 并获得了465 个有效克隆63 个OTUs （Operational Taxonomic Units）。通过16S rRNA 序列与GenBank 已知序列的同源性比较及构建系统进化树的结果显示...  相似文献   

东北地区五大连池湖相沉积物正构烷烃和单体碳同位素特征及其古植被意义     

汪亘  王永莉  孟培  王自翔  孙则朋  杨辉  巩俊成  张虹  吴应琴 《第四纪研究》2015,35(4)

对中国东北地区小兴安岭与松嫩平原过渡带五大连池青石钻孔湖相沉积物进行了有机地球化学分析,检测出丰富的正构烷烃生物标志化合物.本文主要讨论了正构烷烃的分布及其单体碳同位素组成特征.正构烷烃具有前峰型和双峰型两种分布特征,表明其有机质为混合来源,包括低等菌藻类生物和陆生高等植物输入.正构烷烃的分布特征表明,自35.2ka B.P.以来,nC27/nC31和ACL指标共同记录了东北地区小兴安岭与松嫩平原过渡带的植被以草本为主.对C27、C29和C31长链正构烷烃进行了单体碳同位素测定,并利用二元模式估算了C3和C4植物相对生物量,结果表明,自35.2ka B.P.以来,研究区的植被以C3植物为主.期间在典型冷暖气候事件中,受温度变化的影响,C3/C4植物的相对生物量有明显的变化,在全新世大暖期(6.0ka B.P.),受温度升高影响,C3植物的生物量显著减少,C4植物的生物量则明显增加;而在两次典型冷气候事件(中全新世降温事件8.2ka B.P.和新仙女木事件12.9ka B.P.)时期,受温度降低影响,C3植物的生物量有增加的趋势,C4植物的生物量则相对呈减少的趋势;在末次冰盛期21.0ka B.P.时,受明显低温特征的影响,C3植物生物量高达80.0％,这可能是当时低温的气候特征抑制了C4植物的生长.研究结果对探索我国东北地区C3/C4植物分布格局,并为评估未来气候演化对该地区植被格局和农业生产的影响提供科学依据.  相似文献   

云南腾冲青海湖泊沉积物物化参数的特点、环境意义及末次冰消期以来气候环境变化     

刘亚生  常凤琴  张虎才  牛洁  段立曾  李华勇  文新宇  吴汉 《第四纪研究》2015,35(4)

根据对云南腾冲青海湖泊沉积钻孔样品的粒度特征、总有机碳、碳酸盐、磁化率及年代学分析测试,探讨了各指标的变化特点及其环境指示意义,指出了云南高原湖泊沉积物化指标的特殊性及其变化特点.在此基础上,重建了云南腾冲地区末次冰消期(15830a B.P.)以来沉积环境与气候干湿变化历史.通过青海沉积物年代序列的重建和综合各物化参数分析得出,云南腾冲地区自15830a B.P.以来总体呈现冷湿-温湿-暖干-温和偏干的气候演变过程,并可分为4个阶段,即15830～12790a B.P.气候温凉偏湿;12790～4680a B.P.为温暖湿润期,湖泊水位高,气候湿暖,降水多;4680～312a B.P.气候特征呈现出从温湿到暖干气候逐渐演化,降水减少,湖泊水位下降;312a B.P.以来气候特征为前期温和湿润,后期具有暖干化特征,反映了近几十年来全球气候变暖导致的气候变化趋势并叠加了研究区人类活动对区域环境的影响.  相似文献